Multi-Scaled Polymer Nanocomposite Fabrication


Kandemir A. Ç.

8th International Conference on MATERIALS SCIENCE & ENGINEERING, Paris, Fransa, 21 - 22 Eylül 2023, ss.1

  • Yayın Türü: Bildiri / Özet Bildiri
  • Basıldığı Şehir: Paris
  • Basıldığı Ülke: Fransa
  • Sayfa Sayıları: ss.1
  • TED Üniversitesi Adresli: Evet

Özet

Background: So far, artificial composite production routes have been unable to replicate the ductility-

strength balance exhibited by biological entities. A multi-scaled approach should be pursued to

achieve the mechanical properties observed in biological systems. The natural world employs a combination

of diverse length scales, including macro, micro, and nano-scales, to maintain an optimal balance

of various mechanical properties such as strength and toughness. A notable example is the hierarchical

structure of human bones, which consists of seven levels ranging from nanometers to centimeters. The

remarkable aspect of this hierarchical arrangement is that the multi-scaled reinforcements maintain

strength and toughness.

Objective: To achieve the ductility-strength balance of the biological systems.

Methods: The study presents a two-component nanocomposite system, which involves the production

of a macro-scaled biocompatible nanocomposite followed by constructing a micro-scaled nanocomposite

coating with spatially gradient particle distribution on top of it. This composite design imitates the

spatially graded composites found in biological systems that join mechanically distinct entities, such as

bone and cartilage, to produce an incremental change in elastic modulus, preventing stress concentration.

Results: Through mechanical analysis of the gradient coating, it was found that particle concentration

arrangement resulted in an incremental elastic modulus change from the level of polymeric materials

near the bottom to the level of metals/ceramics towards the top of the films leading to 2 orders of magnitude

gradient elastic modulus change.

Conclusion: The macro-component of the multi-scaled composite remained ductile, while the micro-

component surface of it exhibited superior hardness and stiffness, protecting the interiors.